Beilstein J. Nanotechnol.2013,4, 292–299, doi:10.3762/bjnano.4.32
superlattices shown in Figure 4 and Figure 7 as these are projections of curved 2-Dcrystals. In other words, the superlattice fit may actually extend over much larger areas if this curvature is taken into consideration.
In summary, the 2 mm hemispherical eyes of the Mourning Cloak butterfly consist of several
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Figure 1:
Scanning electron micrograph showing the facet structure of the Mourning Cloak butterfly. Note the ...
Beilstein J. Nanotechnol.2011,2, 802–808, doi:10.3762/bjnano.2.88
using scanning tunneling microscopy (STM) at the liquid–solid interface under ambient conditions. The characteristics of the 2-Dcrystals formed on the (0001) plane of highly ordered pyrolitic graphite (HOPG) strongly depend on the length of the π-conjugated oligomer backbone, on the functional groups
ordering on the substrate.
Keywords: 2-Dcrystals; functionalized oligothiophenes; H-bonding; intermolecular interaction; scanning tunneling microscopy; Introduction
In the last few decades conjugated organic polymers and oligomers have attracted a broad interest due to their excellent electronic and
molecular dipole moments.
STM and theoretical parameters of 2-Dcrystals of the investigated carboxylic acid functionalized oligothiophenes HnTCOOH.
Acknowledgements
The authors gratefully acknowledge the financial support of the Deutsche Forschungsgemeinschaft within the collaborative research unit SFB
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Figure 1:
General formula of carboxylic acid functionalized oligothiophenes HnTCOOH.